SPECTRAL SHIFTS OF THE P-AMINOPHENYLTHIYL RADICAL ABSORPTION AND EMISSION IN SOLUTION

被引：28

作者：

MORINE, GH

KUNTZ, RR

机构：

[1] Department of Chemistry, University of Missouri, Columbia

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0009-2614(79)85227-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption and fluorescence spectra of the reactive p-aminophenylthiyl radical were observed in several solvents. Analysis of the spectral shifts yielded dipole moments for the ground and excited states of 4.3 D and 7.3 D, respectively. These values suggest a significant contribution of ionic resonance forms to both states. © 1979.

引用

页码：552 / 554

页数：3

共 21 条

[1]

BLOCK E, 1969, Q REP SULFUR CHEM, V4, P237

[2]

CALVERT JG, 1966, PHOTOCHEMISTRY, P274

[3] FLASH-PHOTOLYSIS OF N-ACETYL-L-TRYPTOPHANAMIDE - ANALYSIS OF TRANSIENTS EMPLOYING VIDICON TUBE DETECTION [J].