SYNTHESIS, STRUCTURE, AND REDUCTION OF THE CYCLOOCTATETRAENE TETRA-ANNELATED WITH BICYCLO[2.2.2]OCTENE FRAMEWORKS

被引：38

作者：

KOMATSU, K ^{[1
]}

NISHINAGA, T ^{[1
]}

AONUMA, S ^{[1
]}

HIROSAWA, C ^{[1
]}

TAKEUCHI, K ^{[1
]}

LINDNER, HJ ^{[1
]}

RICHTER, J ^{[1
]}

机构：

[1] TH DARMSTADT,INST ORGAN CHEM,W-6100 DARMSTADT,GERMANY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 46期

关键词：

REDUCTIVE CYCLIZATION; BICYCLO[2.2.2]OCTENE ANNELATION; X-RAY STRUCTURE; MM CALCULATION; COT DIANION;

D O I：

10.1016/S0040-4039(00)93598-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The COT derivative 3 having rigid sigma-frameworks has been newly synthesized and its X-ray structure determined; 3 is readily reduced to the dianion 3(2-) in spite of severe steric hindrance.

引用

页码：6767 / 6770

页数：4

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