INFLUENCE OF COMPOSITION AND SEGMENT DISTRIBUTION UPON LOWER CRITICAL DEMIXING OF AQUEOUS POLY(VINYL ALCOHOL-STAT-VINYL ACETATE) SOLUTIONS

被引:12
作者
EAGLAND, D
CROWTHER, NJ
机构
[1] Department of Pharmacy, University of Bradford, Bradford
关键词
D O I
10.1016/0014-3057(91)90109-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Cloud point data are presented for a series of 2% w/v solutions of poly(vinyl alcohol-stat-vinyl acetate) copolymers in water and a series of 0.15 M electrolyte solutions; the copolymers were of various compositions and segment length distributions. A relationship has been found showing that the relative sizes of the hydroxyl and acetate sequences, rather than their relative amounts, are the dominant factors in the determination of the lower critical demixing behaviour of this important polymer.
引用
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页码:299 / 301
页数:3
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