A DIRECT CONVERSION OF VIC-DIOLS INTO 1,2-DIKETONES WITH AQUEOUS HYDROGEN-PEROXIDE CATALYZED BY PEROXOTUNGSTOPHOSPHATE (PCWP)

被引：45

作者：

IWAHAMA, T ^{[1
]}

SAKAGUCHI, S ^{[1
]}

NISHIYAMA, Y ^{[1
]}

ISHII, Y ^{[1
]}

机构：

[1] KANSAI UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 564,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 09期

关键词：

D O I：

10.1016/0040-4039(95)00075-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Hydroxy ketones and vic-diols were successfully oxidized to the corresponding diketones with agueous hydrogen peroxide in the presence of a catalytic amount of peroxotungstophosphate (PCWP). This method provides a straightforward route of 1,2-diketones which are difficult to prepare by conventional oxidation of vic-diols.

引用

页码：1523 / 1526

页数：4

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