NONLINEARITY AND NON-EXPONENTIALITY OF PRIMARY RELAXATIONS

被引:75
作者
BOHMER, R
机构
[1] Institut für Festkörperphysik, Technische Hochschule
关键词
D O I
10.1016/0022-3093(94)90499-5
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The glass transformation range of supercooled liquids and amorphous polymers is characterized by a number of unusual properties such as structural state dependence as well as non-Debye and non-Arrhenius behaviors. It is shown how the latter phenomenon, quantified in terms of the fragility index m, is related to the associated spectral width in the linear response regime and to the non-linearity of the enthalpy relaxation for a diverse variety of glass-forming materials.
引用
收藏
页码:628 / 634
页数:7
相关论文
共 41 条
[1]  
Angell C.A., 1985, RELAXATIONS COMPLEX, V3, P3
[2]   PERSPECTIVE ON THE GLASS-TRANSITION [J].
ANGELL, CA .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1988, 49 (08) :863-871
[3]  
BOHMER R, 1994, DISORDER EFFECTS ON RELAXATIONAL PROCESSES, P11
[4]   CORRELATIONS OF THE NONEXPONENTIALITY AND STATE DEPENDENCE OF MECHANICAL RELAXATIONS WITH BOND CONNECTIVITY IN GE-AS-SE SUPERCOOLED LIQUIDS [J].
BOHMER, R ;
ANGELL, CA .
PHYSICAL REVIEW B, 1992, 45 (17) :10091-10094
[5]   NONEXPONENTIAL RELAXATIONS IN STRONG AND FRAGILE GLASS FORMERS [J].
BOHMER, R ;
NGAI, KL ;
ANGELL, CA ;
PLAZEK, DJ .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) :4201-4209
[6]  
BOHMER R, 1989, J CHEM PHYS, V91, P3111, DOI 10.1063/1.456933
[7]  
BOTTCHER CJF, 1978, THEORY ELECTRIC POLA, V2
[8]   STRUCTURAL RELAXATION IN VITREOUS SILICA [J].
BUCHENAU, U ;
ZHOU, HM ;
NUCKER, N ;
GILROY, KS ;
PHILLIPS, WA .
PHYSICAL REVIEW LETTERS, 1988, 60 (13) :1318-1321
[9]  
CAILLOT E, 1991, CR ACAD SCI II, V312, P447
[10]   NON-ARRHENIUS RESPONSE OF GLASS-FORMING LIQUIDS [J].
CHAMBERLIN, RV .
PHYSICAL REVIEW B, 1993, 48 (21) :15638-15645