PREPARATION AND STRUCTURE OF [MO6CL8(CH3CN)(6)](SBCL6)(4)CENTER-DOT-2ETOH

被引：27

作者：

EHRLICH, GM

WARREN, CJ

HAUSHALTER, RC

DISALVO, FJ

机构：

[1] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853

[2] NEC RES INST,PRINCETON,NJ 08540

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 16期

关键词：

D O I：

10.1021/ic00120a042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of an acetonitrile-ligated molybdenum chloride cluster has been accomplished by the reaction of (Bu(4)N)(2)Mo6Cl8(CF3SO3)(6) and KSH in ethanol, followed by the extraction of the resulting product with SbCl5 in acetonitrile. The cluster, [Mo6Cl8(CH3CN)(6)]-(SbCl6)(4) . 2EtOH (1), consists of an octahedral arrange ment of six molybdenum atoms with eight chlorine atoms bridging the faces of the octahedron. A single acetonitrile ligand completes the coordination environment of each molybdenum atom and is positioned perpendicular to each of the six faces of the Cl-8 cube.

引用

页码：4284 / 4286

页数：3

共 9 条

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