THE USE OF THE NOVEL OXIDIZING REAGENT TRIPHENYLARSINE DIIODINE IN THE REACTION WITH DICOBALT OCTACARBONYL TO PRODUCE A NEW-TYPE OF COMPLEX [(PH3ASI)2I][CO(ASPH3)I3]

被引：13

作者：

GODFREY, SM ^{[1
]}

LANE, HP ^{[1
]}

MACKIE, AG ^{[1
]}

MCAULIFFE, CA ^{[1
]}

PRITCHARD, RG ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 15期

关键词：

D O I：

10.1039/c39930001190

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ph3AsI2 oxidises Co2(CO)8 in a 6:1 molar ratio lo produce the novel complex [(Ph3AsI)2I][Co(AsPh3)I3] in quantitative yield, the first crystallographically characterised complex containing a cobalt(II)-tertiary arsine bond and the unusual linear cation [Ph3As-I-I-I-AsPh3]+.

引用

页码：1190 / 1191

页数：2

共 17 条

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