CRYSTAL AND MOLECULAR-STRUCTURE OF TETRATHIOCYANATO TETRAKIS (TRIPHENYLPHOSPHINE OXIDE URANIUM(IV)

被引：10

作者：

BOMBIERI, G ^{[1
]}

DEPAOLI, G ^{[1
]}

FORSELLINI, E ^{[1
]}

BROWN, D ^{[1
]}

机构：

[1] AERE,DIV CHEM,HARWELL OX11 0RA,OXFORDSHIRE,ENGLAND

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 09期

关键词：

D O I：

10.1016/0022-1902(79)80046-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the title compound has been determined from three dimensional X-ray diffraction data. The compound crystallises in space group P1 - with a = 26.057(12), b = 23.058(11), c = 13.845(7) A ̊, α = 90.6(1)°, β = 102.5(1)°, γ = 114.6(1)°, and Z = 4. The asymmetric unit comprises two independent U(NCS)4(tppo)4 molecules in each of which the coordination polyhedron around the uranium atom is close to square antiprismatic. © 1979.

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页码：1315 / 1320

页数：6

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