A BIOMIMETIC PARTIAL SYNTHESIS OF THE RED CHLOROPHYLL-A CATABOLITE FROM CHLORELLA-PROTOTHECOIDES

被引：15

作者：

ITURRASPE, J ^{[1
]}

GOSSAUER, A ^{[1
]}

机构：

[1] UNIV FRIBOURG,INST ORGAN CHEM,RTE DU MUSEE,CH-1700 FRIBOURG,SWITZERLAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 33期

关键词：

D O I：

10.1016/S0040-4020(01)89871-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The red bilin derivative which is excreted in the culture medium by Chlorella protothecoides when this microalgae is grown in a medium rich in glucose but poor in nitrogen has been synthesized in two steps from one of the products of photo-oxidation of the Cd(II) complex of pyropheophorbide-a methyl ester. Under the same conditions, the Zn(II) complex of the latter is transformed into a blue bilin derivative which is an isomer of the foregoing chlorophyll-a catabolite.

引用

页码：6807 / 6812

页数：6

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