EFFECTS OF A NAPHTHYL GROUP UPON THE STABILITY OF AROXYLOXYL RADICALS

被引：21

作者：

TATENO, T

SAKURAGI, H

TOKUMARU, K

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.1883

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Naphthoyloxyl and 2-naphthoyloxyl radicals decarboxylate with higher activation energies than the unsubstituted benzoyloxyl radical (PhCO2.) particularly in acetonitrile, which indicates that the conjugative electron delocalization contributes to the stabilization of these radicals.

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页码：1883 / 1886

页数：4

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