ORGANOMETAL CHEMISTRY OF TECHNETIUM .8. TECHNETIUM(I) CARBONYL-COMPLEXES WITH POLYPYRAZOL-1-YLBORATO LIGANDS IN COMPARISON WITH MN AND RE ANALOGS

被引：49

作者：

JOACHIM, JE

APOSTOLIDIS, C

KANELLAKOPULOS, B

MAIER, R

MARQUES, N

MEYER, D

MULLER, J

DEMATOS, AP

NUBER, B

REBIZANT, J

ZIEGLER, ML

机构：

[1] INST HEISSE CHEM,KERNFORSCHUNGSZENTRUM KARLSRUHE,POSTFACH 3640,W-7500 KARLSRUHE,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

[3] EUROPA INST TRANSURANE,W-7500 KARLSRUHE,GERMANY

[4] LNETI,ICEN,DEPT QUIM,P-2686 SACAVEM,PORTUGAL

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 448卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80076-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds HB(C3H3N2)3Tc(CO)3 and HB(3,5-Me2C3HN2)3Tc(CO)3 have been synthesized for the first time, and their molecular and crystal structure as well as the structures of the known analogous compounds of manganese and rhenium determined by single-crystal X-ray diffraction. The IR-, H-1-NMR-, C-13-NMR-, UV- and EI-MS-spectroscopic data are discussed in correlation to the electric dipole moment and the charge distribution within the molecule.

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页码：119 / 129

页数：11

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