AN AB-INITIO STUDY ON THE MECHANISM OF THE ALKENE ISOCYANATE CYCLOADDITION REACTION TO FORM BETA-LACTAMS

被引：27

作者：

COSSIO, F ^{[1
]}

LECEA, B ^{[1
]}

LOPEZ, X ^{[1
]}

ROA, G ^{[1
]}

ARRIETA, A ^{[1
]}

UGALDE, JM ^{[1
]}

机构：

[1] EUSKAL HERRIKO UNIBERTSITATEA,FAK FARMAZI,E-01007 VITORIA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001450

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ab initio calculations predict that the [2 + 2] reaction between isocyanates and alkenes to form beta-lactams is a cycloaddition which takes place through a concerted suprafacial mechanism.

引用

页码：1450 / 1452

页数：3

共 42 条

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