NMR ASSIGNMENTS FOR THE ALDOPENTOSES

被引：25

作者：

BENESI, AJ

FALZONE, CJ

BANERJEE, S

FARBER, GK

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIV PK,PA 16802

[2] PENN STATE UNIV,CTR BIOMOLEC STRUCT & FUNCT,DAVEY LAB 152,UNIV PK,PA 16802

来源：

CARBOHYDRATE RESEARCH | 1994年 / 258卷

关键词：

D O I：

10.1016/0008-6215(94)84072-5

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The H-1 and C-13 NMR assignments for the simple aldopentopyranoses in (H2O)-H-2 were made using high field 2D NMR spectroscopy. The furanose forms of ribose were also tentatively assigned. The 2D techniques used to assign the resonances include the HMQC, HMBC, 2QF-COSY, TOCSY, 2Q, and INADEQUATE experiments. Selective 1D TOCSY experiments were also necessary to assign the crowded proton spectrum of ribose.

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页码：27 / 33

页数：7

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