SELECTIVE ISOMERIZATION OF BUTENE TO ISOBUTENE

被引：37

作者：

CHENG, ZX

PONEC, V

机构：

[1] Gorlaeus Laboratories, Leiden University, RA Leiden, 2300

来源：

CATALYSIS LETTERS | 1994年 / 25卷 / 3-4期

关键词：

SKELETAL ISOMERIZATION; N-BUTENE; CR; MO; W AND AL OXIDES;

D O I：

10.1007/BF00816313

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

To identify the elements active for the skeletal isomerization of n-butene, a search along the periods of the periodic system has been performed. It is shown that the group VIA (Cr, Mo and W) oxides and the Al oxide are potentially active catalysts. The reaction mechanism and the nature of the active sites are also discussed in relation to the information from the literature.

引用

页码：337 / 349

页数：13

共 15 条

[1] Baker B. G., 1986, U.S. Patent, Patent No. 4610975
[2] BAKER BG, 1987, CATALYSIS AUTOMATIVE, P483
[3] CHEMISTRY OF OLEFINS AT METAL-OXIDE SURFACES - A TOOL FOR SURFACE SCIENCE INVESTIGATION OF OXIDE CATALYSTS
BUSCA, G
LORENZELLI, V
RAMIS, G
ESCRIBANO, VS
[J]. MATERIALS CHEMISTRY AND PHYSICS, 1991, 29 (1-4) : 175 - 189
[4] CHENG ZX, 1993, UNPUB J CATAL
[5] CHOUDHARY VR, 1975, PROCESS RES DEV, V14, P227
[6] SKELETAL ISOMERIZATION OF HYDROCARBONS OVER ZIRCONIUM-OXIDE PROMOTED BY PLATINUM AND SULFATE ION
EBITANI, K
KONISHI, J
HATTORI, H
[J]. JOURNAL OF CATALYSIS, 1991, 130 (01) : 257 - 267
[7] ESNCHEZ VS, 1991, J PHYS CHEM-US, V9, P5541
[8] SKELETAL ISOMERIZATION OF HYDROCARBONS ON MOLYBDENUM CATALYSTS .3. CATALYTIC STUDY OF ALUMINA-SUPPORTED CATALYSTS
HOLL, Y
GARIN, F
MAIRE, G
MULLER, A
ENGELHARD, PA
GROSMANGIN, J
[J]. JOURNAL OF CATALYSIS, 1987, 104 (01) : 225 - 232
[9] SKELETAL ISOMERIZATION OF HYDROCARBONS ON MOLYBDENUM CATALYSTS .1. X-RAY PHOTOELECTRON-SPECTROSCOPY STUDY OF ALUMINA-SUPPORTED CATALYSTS
HOLL, Y
TOUROUDE, R
MAIRE, G
MULLER, A
ENGELHARD, PA
GROSMANGIN, J
[J]. JOURNAL OF CATALYSIS, 1987, 104 (01) : 202 - 210
[10] SKELETAL ISOMERIZATION OF HYDROCARBONS ON MOLYBDENUM CATALYSTS .2. CATALYTIC STUDY OF UNSUPPORTED CATALYSTS - FILM AND POWDER
HOLL, Y
GARIN, F
MAIRE, G
MULLER, A
ENGELHARD, PA
GROSMANGIN, J
[J]. JOURNAL OF CATALYSIS, 1987, 104 (01) : 211 - 224

← 1 2 →