PREPARATION AND STRUCTURE OF SOME TRICYCLO[3.2.1.02,4]OCTANE DERIVATIVES

被引：52

作者：

CLARKE, SC

FRAYNE, KJ

JOHNSON, BL

机构：

[1] Department of Organic Chemistry, University of Western Australia, Nedlands

来源：

TETRAHEDRON | 1969年 / 25卷 / 06期

关键词：

D O I：

10.1016/S0040-4020(01)82700-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reaction of 1,2,3,4-tetrachloro-5,5-< limethoxycyclopenta-1,3-diene with cyclopropene has been utilized to furnish some endo-tricyclo[3.2.1.02,4]octane derivatives. Several exo-tricyclo[3.2.1.2,4]octane derivatives were synthesized from known precursors using standard reactions. The stereochemistry of the tetracyclic alcohol, resulting (ultimately) from the reaction of 7-norbornadienyl acetate with diazomethane, is discussed. The PMR spectra of a number of tricyclo[3.2.1.02,4]octane derivatives are presented and discussed with reference to configurational assignment. © 1969.

引用

页码：1265 / &

共 45 条

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