STUDIES WITH DITHIZONE .13. EXTRACTION OF METHYL- BENZYL- AND P-BROMOPHENYLMERCURY(2) DITHIZONATES

被引:12
作者
IRVING, HMN
KIWAN, AM
机构
[1] Department of Inorganic and Structural Chemistry, The University, England
关键词
D O I
10.1016/S0003-2670(01)95595-3
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
1:1 Complexes are formed between dithizonate ions, HDz-, and certain organomercury cations, RHg+ (R = methyl, benzyl, and p-bromophenyl). Their absorption spectra in carbon tetrachloride and the effects of pH on the percentage extracted from aqueous buffers containing, or free from, auxiliary complexing agents have been studied. The anomalous behaviour previously reported could not be confirmed. © 1969.
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页码:243 / &
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