METAL-COMPLEXES OF BREDT OLEFINS - SYNTHESIS AND STRUCTURE OF BICYCLO[4.2.1]NON-1(8)-ENEBIS(TRIPHENYL-PHOSPHANE)PLATINUM(0)

被引：23

作者：

STAMM, E

BECKER, KB

ENGEL, P

ERMER, O

KEESE, R

机构：

[1] UNIV BERN,INST ORGAN CHEM,CH-3012 BERN,SWITZERLAND

[2] UNIV BERN,INST MINERAL PETROG,CH-3012 BERN,SWITZERLAND

[3] UNIV BASEL,INST ORGAN CHEM,CH-4056 BASEL,SWITZERLAND

[4] RUHR UNIV BOCHUM,CHEM ABT,D-4630 BOCHUM,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 09期

关键词：

D O I：

10.1002/anie.197906851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reversible stabilization of a Bredt olefin has been accomplished for the first time with a platinum(0) compound. In complex 3 (X‐ray structure analysis) the olefin has the same conformation as free 2 (force field calculations). Treatment of the complex with CS2 regenerates isomer‐free 2. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：685 / 686

页数：2

共 17 条

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