C-13 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF ACYCLIC CARBOHYDRATE-DERIVATIVES - ALDITOLS, 1,2-BIS(PHENYLHYDRAZONES), AND DITHIOACETALS

被引：61

作者：

SCHNARR, GW ^{[1
]}

VYAS, DM ^{[1
]}

SZAREK, WA ^{[1
]}

机构：

[1] QUEENS UNIV, DEPT CHEM, KINGSTON K7L 3N6, ONTARIO, CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 02期

关键词：

D O I：

10.1039/p19790000496

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbon-13 n.m.r. spectra of acyclic carbohydrate derivatives, namely alditols, 1,2-bis(phenylhydrazones), dithioacetals, and related acyclic sugar derivatives, are reported. The study has corroborated earlier results, based on 1H n.m.r. investigations, on the conformational behaviour of such compounds in solution. Application of this technique in elucidation of regiospecificity of oxidation of alditols by Acetobacter suboxydans is discussed.

引用

页码：496 / 503

页数：8

共 79 条

[1] C-13 FOURIER TRANSFORM NUCLEAR MAGNETIC RESONANCE .6. STRATEGIES IN APPLICATION OF PARTIALLY RELAXED FOURIER TRANSFORM NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY IN ASSIGNMENTS OF C-13 RESONANCES OF COMPLEX MOLECULES - STACHYOSE [J].

ALLERHAND, A ;

DODDRELL, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (11) :2777-+

[2] CONFORMATIONAL-ANALYSIS IN CARBOHYDRATE-CHEMISTRY .3. C-13 NMR-SPECTRA OF HEXULOSES [J].

ANGYAL, SJ ;

BETHELL, GS .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (06) :1249-1265

[3] COMPLEXES OF CARBOHYDRATES WITH METAL CATIONS .3. CONFORMATIONS OF ALDITOLS IN AQUEOUS-SOLUTION [J].

ANGYAL, SJ ;

GREEVES, D ;

MILLS, JA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1974, 27 (07) :1447-1456

[4] CONFORMATIONS OF ACYCLIC SUGAR DERIVATIVES - ACETYLATED METHYL 5-HEXULOSONATES AND KETO-HEXULOSES [J].

ANGYAL, SJ ;

JAMES, K .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (06) :1223-&

[5]

Asai T., 1968, ACETIC ACID BACTERIA

[6] CONCERNING STEREOCHEMICAL ASSIGNMENTS FROM C-13 SPECTRA OF SYSTEMS EXPERIENCING GAMMA SUBSTITUENT EFFECTS - DESHIELDING ANTIPERIPLANAR INTERACTIONS CAN MISLEAD UNWARY [J].

AYER, WA ;

BROWNE, LM ;

FUNG, S ;

STOTHERS, JB .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (20) :3272-3275

[7]

AZARNIA N, 1970, JOINT AM CHEM SOC CI

[8] SYNTHETIC NUCLEOSIDES .54. FACILE DISPLACEMENT REACTIONS IN D-MANNITOL SERIES .1. [J].

BAKER, BR ;

HAINES, AH .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (02) :438-&

[9] CRYSTAL STRUCTURE OF GALACTITOL [J].

BERMAN, HM ;

ROSENSTEIN, RD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :435-+

[10] CRYSTAL STRUCTURES OF ALPHA' AND BETA FORMS OF D-MANNITOL [J].

BERMAN, HM ;

JEFFREY, GA ;

ROSENSTEIN, RD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :442-+

← 1 2 3 4 5 6 7 8 →