ANALYSIS OF THE ABSORPTION AND MAGNETIC CIRCULAR-DICHROISM SPECTRA OF THE HYPERSENSITIVE BAND IN (H5C5H5)HO(H8C8H8)

被引:2
作者
HOLLEBONE, BR [1 ]
STILLMAN, MJ [1 ]
机构
[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 5B7,ONTARIO,CANADA
关键词
D O I
10.1016/0009-2614(79)85008-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solution MCD spectrum of (h5C5H5)Ho(III)(h8C8H8) is dominated by C terms but displays distinct A term under the hypersensitive 5I8 - 5G6 transition. Intermediate field analysis suggests this transition originates from the first electronic excited state and is enhanced by τ cyclopentadienyl ligand polarization. © 1979.
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页码:248 / 251
页数:4
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