A FACILE SYNTHESIS OF IMINOSILANES - CRYSTAL-STRUCTURE OF (ME3C)2(THF)SI=N-SIME(CME3)2

被引：36

作者：

WALTER, S ^{[1
]}

KLINGEBIEL, U ^{[1
]}

SCHMIDTBASE, D ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST INORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 412卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86076-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aminofluorosilane 1 (Me3C)2SiFNHSiMe(CMe3)2 is formed by treatment of (Me3C)2SiF2 with (Me3C)2MeSiNHLi. The lithium derivative of 1, (Me3C)2SiFLi(THF)2NSiMe(CMe3)2, 3, is formed by treatment with n-C4H9Li. Treatment of 3 with Me3SiCl gives Me3SiF, LiCl and the iminosilane (Me3C)2(THF)Si = N-SiMe(CMe3)2, 4. Compound 4 can be distilled and recrystallized from benzene. Its crystal structure has been determined.

引用

页码：319 / 326

页数：8

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