PREPARATION AND X-RAY STRUCTURES OF TRIDENTATE (N,N,S) COMPLEXES OF THE DIAZENE TRANS-[PHSNC(4-MEC6H4)N=NC(4-MEC6H4)NSPH] WITH PLATINUM AND PALLADIUM

被引：9

作者：

CHIVERS, T

MCGREGOR, K

PARVEZ, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 12期

关键词：

D O I：

10.1039/c39930001021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of trans-[PhSNC(MeC6H4)N=NC(MeC6H4)NSPh] with (C2H4)Pt(PPh3)2 or Pd(PPh3)4 in toluene produces the complexes M{PhSNC(MeC6H4)N-NC(MeC6H4)NSPh}(PPh3) (M = Pt, Pd) in which the ligand is bonded to the metal in a tridentate (N,N,S) fashion and the diazine is formally reduced to an azine.

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页码：1021 / 1023

页数：3

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