LARGE, INVERSE SOLVENT ISOTOPE EFFECTS - A SIMPLE TEST FOR THE E1CB MECHANISM

被引：31

作者：

KEEFFE, JR

JENCKS, WP

机构：

[1] BRANDEIS UNIV,GRAD DEPT BIOCHEM,WALTHAM,MA 02154

[2] CALIF STATE UNIV SAN FRANCISCO,DEPT CHEM,SAN FRANCISCO,CA 94132

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1981年 / 103卷 / 09期

关键词：

D O I：

10.1021/ja00399a074

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2457 / 2459

页数：3

共 8 条

[1] CATALYSIS OF THE REVERSIBLE ELIMINATION-REACTIONS OF SUBSTITUTED N-(BETA-PHENYLETHYL)QUINUCLIDINIUM IONS IN AQUEOUS-SOLUTION [J].

ALUNNI, S ;

JENCKS, WP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (06) :2052-2060

[2]

BRESLOW R, 1964, TETRAHEDRON LETT, P399

[3] EVIDENCE FOR A CHANGE IN RATE-DETERMINING STEP IN ACID-CATALYZED HYDROLYSIS OF A VINYL ETHER [J].

COOPER, JD ;

VITULLO, VP ;

WHALEN, DL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (23) :6294-&

[4] ENERGETICS OF TRIOSEPHOSPHATE ISOMERASE - DEUTERIUM-ISOTOPE EFFECTS IN ENZYME-CATALYZED REACTION [J].

LEADLAY, PF ;

ALBERY, WJ ;

KNOWLES, JR .

BIOCHEMISTRY, 1976, 15 (25) :5617-5620

[5] THE MECHANISM OF OXIDATION OF CYCLOHEXANONE UNDER ACID CONDITIONS .4. PRIMARY AND SOLVENT ISOTOPE EFFECTS ON OXIDATIONS OF KETONES AND ENOLS - AN INDIRECT DETERMINATION OF THE RELATIVE ENOL CONTENTS OF ISOTOPICALLY SUBSTITUTED KETONES IN WATER AND DEUTERIUM-OXIDE, AND OF THE SOLVENT ISOTOPE EFFECTS FOR THE ELECTRON-TRANSFER PROCESSESTI [J].

LITTLER, JS ;

QUICK, GR ;

WOZNIAK, D .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (04) :657-661

[6] KETO-ENOL TRANSFORMATION OF 1,2-CYCLOHEXANEDIONE .2. ACID CATALYSIS IN STRONGLY ACIDIC MEDIA [J].

LONG, FA ;

BAKULE, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (15) :2313-+

[7] BETA-ELIMINATION OF 9-FLUORENYLMETHANOL IN AQUEOUS SOLUTION - AN E1CB MECHANISM [J].

OFERRALL, RA ;

SLAE, S .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (02) :260-&

[8]

OFERRALL RAM, 1977, P R IR ACAD B, V77, P513

← 1 →