SYNTHESIS OF NEW 5-ATOM-LINKED CAPPED PORPHYRINS

被引：15

作者：

MA, WP ^{[1
]}

SLEBODNICK, C ^{[1
]}

IBERS, JA ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 23期

关键词：

D O I：

10.1021/jo00075a031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of three new five-atom-linked ''capped'' porphyrins, 6, 12, and 18, are reported. The general synthetic procedure involves synthesis of a tetraaldehyde ''cap'' by reacting the five-atom ''arm'' with 1,2,4,5-tetrahydroxybenzene in DMSO solvent in the presence of KOH. The tetraaldehyde and pyrrole are reacted to form the capped porphyrin. These compounds are useful as models for the active sites of heme proteins.

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页码：6349 / 6353

页数：5

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