SURFACE ACOUSTIC-WAVE PROBE FOR CHEMICAL-ANALYSIS .1. INTRODUCTION AND INSTRUMENT DESCRIPTION

被引:393
作者
WOHLTJEN, H [1 ]
DESSY, R [1 ]
机构
[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061
关键词
D O I
10.1021/ac50045a024
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Surface acoustic waves are easily propagated along a quartz or lithium niobate surface. Interdigitized finger transducers serve as transmitters of 30-60 MHz SAW waves toward an equivalent detector. Surface molecules predictably affect the wave propagation. Circuitry has been built to measure such interactions by changes in amplitude or phase-angle shift of the SAW, or the alteration of the resonance frequency when the device is part of a “tank” circuit. Amplitude response is proportional to the pressure of gaseous molecules in the environment. For a given gas, the response factor is proportional to (molecular weight)1/2. Large linear frequency shifts were noted as ambient pressures changed. Amplitude measurements on quartz have the best S/N ratio (566). Limited data suggest that LiNbO3 devices have considerably better S/N ratios. © 1979, American Chemical Society. All rights reserved.
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页码:1458 / 1464
页数:7
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