LITHIUM BIS(DI-TERT-BUTYLFLUOROSILYL)PHOSPHIDE, A CYCLIC DIPOLAR ION

被引：12

作者：

KLINGEBIEL, U ^{[1
]}

MEYER, M ^{[1
]}

PIEPER, U ^{[1
]}

STALKE, D ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 408卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)80097-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We present the synthesis and X-ray structure of lithiumbis(di-tert-butylfluorosilyl)phosphide (3). The molecule possesses a unique dipolar cyclic structure without direct Li-P contact. The Si-P--Si bond angle is approximately 100-degrees, similar to that of other lithiumfluorosilylphosphides (I-IV). The energy of 3, calculated by ab initio methods, explains the invariance of the angle, which allows a comparison with the related amides.

引用

页码：19 / 25

页数：7

共 10 条

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