PENTAPHOSPHA AND HEXAPHOSPHA FERROCENES AS LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF [FE(ETA-5-P3C2(T)BU2)2W(CO)5], [FE(ETA-5-P3C2(T)BU2)(ETA-5-P2C3(T)BU3)W(CO)5] AND THE NOVEL TRIRUTHENIUM CARBONYL CLUSTER COMPLEX [FE(ETA-5-P3C2(T)BU2)2RU3(CO)10] CONTAINING 2 INTERLINKED ETA-5-P3C2(T)BU2 RING-SYSTEMS

被引：32

作者：

BARTSCH, R ^{[1
]}

GELESSUS, A ^{[1
]}

HITCHCOCK, PB ^{[1
]}

NIXON, JF ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)80106-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The lone-pair electrons of one of the two directly bonded phosphorus atoms of the P3C2tBu2 ring in the penta- or hexaphosphaferrocene complexes [Fe(eta-5-P3C2tBu2)(eta-5-P2C3tBu3)] and [Fe(eta-5-P3C2tBu2)2] can ligate to other metal centres to afford novel bi- and tetrametallic complexes, whose structures have been elucidated by NMR and single crystal X-ray crystallographic studies.

引用

页码：C10 / C14

页数：5

共 6 条

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[3] HEXA-PHOSPHORUS ANALOGS OF METALLOCENES - SYNTHESIS OF THE 1ST PARAMAGNETIC SANDWICH COMPLEX CONTAINING 2 ETA-5-1,2,4-TRIPHOSPHACYCLOPENTADIENYL RINGS - CRYSTAL AND MOLECULAR-STRUCTURES OF [CR(ETA-5-C2(BU-TERT)2P3)2] [J].

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[4] 1ST EXAMPLES OF ETA-1-LIGATED 1,2,4-TRIPHOSPHACYCLOPENTADIENYL RING-SYSTEMS - SYNTHESIS AND FLUXIONAL BEHAVIOR OF TRANS-[MCI(C2R2P3)(PET3)2], (R=BUT,ADAMANTYL),(M=PD,PT) - CRYSTAL AND MOLECULAR-STRUCTURES OF TRANS-[PTX(C2BUT2P3)(PR3)2], (X=CL,R=ET, X=I,R=PH) [J].

BARTSCH, R ;

CARMICHAEL, D ;

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SILLETT, GJD .

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[5] 1ST EXAMPLE OF A 1,2,4-TRIPHOSPHABUTA-1,3-DIENE COMPLEX - SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF [CO(ETA-5-C2BUT2P3)(ETA-4-C2BUT2HP3)] [J].

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[6]

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