REMARKABLE ALPHA-REGIOSELECTIVITY IN THE RHODIUM-CATALYZED HYDROFORMYLATION OF 2-VINYLPYRIDINE

被引：21

作者：

SETTAMBOLO, R

PUCCI, S

BERTOZZI, S

LAZZARONI, R

机构：

[1] CNR,CTR STUDIO MACROMOLEC STEREODINATE & OTTICAMEN,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[2] CNR,IST CHIM QUANTIST & ENERGET MOLEC,I-56126 PISA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 489卷 / 1-2期

关键词：

HYDROFORMYLATION; VINYLPYRIDINES; ALPHA-REGIOSELECTIVITY; 2-(2-PYRIDYL)PROPANAL; RHODIUM; CATALYSIS;

D O I：

10.1016/0022-328X(94)05293-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [{Rh(CO)(2)Cl}(2)]/PPhMe(2)-catalyzed hydroformylation of 2-vinylpyridine gives the branched aldehyde 2-(2-pyridyl)propanal in good yield and 99% alpha-regioselectivity.

引用

页码：C50 / C51

页数：2

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