TITANIUM TETRAFLUORIDE - A SURPRISING SIMPLE COLUMN STRUCTURE

被引：50

作者：

BIALOWONS, H ^{[1
]}

MULLER, M ^{[1
]}

MULLER, BG ^{[1
]}

机构：

[1] UNIV GIESSEN,INST ANORGAN & ANALYT CHEM,D-35392 GIESSEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 07期

关键词：

TIF4; PREPARATION; SINGLE CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19956210720

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the first time single crystals of TiF4 have been obtained by solvothermal decomposition of (O-2)(2)Ti7F30 in anhydrous HE The colourless, transparent needles crystallize orthorhombic in spacegroup Pnma-D-2h(16) (No.62) with a = 2281.1, b = 384.8, c = 956.8 pm, Z = 12. The new type of structure is dominated by isolated columns of corner-linked TiF6-octahedra.

引用

页码：1227 / 1231

页数：5

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