PENTACHLOROPHENOL-INDUCED RELEASE OF SOIL ORGANICS AND COLLOIDS

被引:13
作者
GALIL, NI [1 ]
NOVAK, JT [1 ]
机构
[1] VIRGINIA POLYTECH INST & STATE UNIV, DEPT CIVIL ENGN, BLACKSBURG, VA 24061 USA
关键词
HYDROPHOBIC ORGANIC COMPOUNDS; PENTACHLOROPHENOL; FULVIC ACIDS; COSOLVENCY; ADSORPTION;
D O I
10.1016/0043-1354(94)00311-T
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
It was observed that when dissolved pentachlorophenol (PCP) at aqueous concentration between I and 10 mg/l was contacted with soil, organics from the soil surface were solubilized and soil colloids were stabilized. The stable soil colloids, identified microscopically as clays, retained beween 2.6% and 13% of the PCP depending on the PCP added and the soil type. The soil organics which were released from the soil surface, tentatively characterized as fulvic acids, increased with increasing PCP additions. These soil organics enhanced the solubility and decreased adsorption of pentachlorophenol due to cosolvency. These interactions appear to provide a mechanism for enhanced transport of contaminants in both ground and surface water through both colloidal transport and increased solubility when an organic contaminant is discharged or leaks into a soil-water system.
引用
收藏
页码:1533 / 1540
页数:8
相关论文
共 23 条
[1]  
Abdul, Gibson, Rai, Use of humic acid solution to remove organic contaminants from hydrogeologic systems, Envir. Sci. Technol., 24, pp. 328-333, (1990)
[2]  
Chiou, Malcolm, Brinton, Kile, Water solubility enhancement of some organic pollutants and pesticides by dissolved humic and fulvic acids, Envir. Sci. Technol., 20, pp. 502-508, (1986)
[3]  
Chiou, Kile, Brinton, Malcolm, Leenheer, A comparison of water solubility enhancements of organic solutes by aquatic humic acids, Environmental Science & Technology, 21, pp. 1232-1234, (1987)
[4]  
Choi, Aomine, Effects of the soil on the activity of Pentachlorophenol, Soil Science and Plant Nutrition, 16, pp. 255-260, (1972)
[5]  
Choi, Aomine, Adsorption of Pentachlorophenol by soils, Soil Science and Plant Nutrition, 20, pp. 135-144, (1974)
[6]  
Choi, Aomine, Mechanisms of Pentachlorophenol adsorption by soils, Soil Science and Plant Nutrition, 20, pp. 371-379, (1974)
[7]  
Crane, Sorption of pentachlorophenol to humic acids and subsequent effects on biodegradation and solvent extraction, M.Sc. thesis, (1992)
[8]  
Davies, Loss-on-ignition as an estimate of soil organic matter, Soil Science Society of America Journal, 38, pp. 150-151, (1974)
[9]  
Johnson, Brilliante, Isabelle, Houck, Pankow, Migration of chlorophenolic compounds at the chemical waste disposal site at Alkali Lake Oregon—2. Contaminant Distribution, Transport and Retardation, Groundwater, 23, pp. 652-666, (1985)
[10]  
Lee, Rao, Nkedi-Kizza, Delfino, Influence of solvent and sorbent characteristics on distribution of Pentachlorophenol in octanol-water and soil-water systems, Envir. Sci. Technol., 24, pp. 654-661, (1990)