SOME NEW POLYHALOARYL DERIVATIVES OF TIN

被引:20
作者
CHIVERS, T
机构
[1] Department of Chemistry, University of British Columbia, Vancouver 8, BC
关键词
D O I
10.1016/S0022-328X(00)87755-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Some new polyhaloaryltin compounds, 2-BrC6F4SnMe3, (2-BrC6F4)2SnMe2, 1,2-C6F4(SnMe3)2, 1,4-C6F4(SnMe3)2 and 4-HC6F4SnMe3 have been synthesised from the appropriate polyhaloaryl-lithium reagent and dimethyl- or trimethyltin chloride. 1H and 19F NMR data for these compounds are reported. There is no evidence for intramoleeular Sn-Br interaction in 2-BrC6F4SnMe3 from the 1H NMR spectrum at - 60°. © 1969.
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页码:75 / &
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