PHASE-TRANSITION IN NASN2(PO4)3 AND THERMAL-EXPANSION OF NAM2(IV)(PO4)3 - MIV = TI, SN, ZR

被引：45

作者：

RODRIGO, JL ^{[1
]}

ALAMO, J ^{[1
]}

机构：

[1] UNIV VALENCIA,DEPT QUIM INORGAN,DR MOLINER 50,E-46100 BURJASSOT,SPAIN

来源：

MATERIALS RESEARCH BULLETIN | 1991年 / 26卷 / 06期

关键词：

SODIUM; TITANIUM; TIN; ZIRCONIUM; PHOSPHATES; NZP;

D O I：

10.1016/0025-5408(91)90187-Q

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Na Sn2 (PO4)3 presents a fast and reversible second order phase transition about 575-degrees-C. Both phases above and below the transition point are rhombohedral. The high temperature phase is isostructural with Na Ti2 (PO4)3 and Na Zr2 (PO4)3, NZP structure. The lattice thermal expansion of these three compounds has been determined from x-ray diffraction data at different temperatures ranging from room temperature up to 1000-degrees-C. Differences in behaviour are discussed in relation to the structure.

引用

页码：475 / 480

页数：6

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