QUADRUPOLE EFFECTS OF SPIN-3/2 NUCLEI ON THE SOLID-STATE MAGIC-ANGLE-SPINNING NUCLEAR-MAGNETIC-RESONANCE SPECTRA OF SPIN-1/2 NUCLEI - DEVIATIONS FROM 1ST-ORDER THEORY AND IMPLICATIONS CONCERNING THE SIGN OF THE INDIRECT COUPLING-CONSTANT

被引：38

作者：

ALARCON, SH

OLIVIERI, AC

HARRIS, RK

机构：

[1] FAC CIENCIAS BIOQUIM & FARMACEUT ROSARIO,DEPT QUIM ANALIT,SUIPACHA531,RA-2000 ROSARIO,ARGENTINA

[2] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1993年 / 2卷 / 06期

关键词：

SPIN-3/2; NUCLEI; SPIN-1/2; 1ST-ORDER THEORY; COUPLING CONSTANT;

D O I：

10.1016/0926-2040(83)90004-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of the interaction between spin-3/2 and spin-1/2 nuclei on solid-state magic-angle spinning nuclear magnetic resonance (MAS NMR) spectra of the latter is studied in cases where deviations from first-order theory are expected. A comparison is made between the exact and first-order perturbation approaches. Both dipolar and indirect (iso- and anisotropic) coupling interactions are considered. Implications regarding C-13, Cl-35, Cl-37, P-31, Cu-63, Cu-65, and Sn-119, Cl-35, Cl-37 cases are discussed. It is shown that in the latter two cases the sign of the indirect coupling constant J can be derived.

引用

收藏

页码：325 / 334

页数：10

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