The Fe-N bond lengths, the "ionic radii" of iron (II), and the crystal field parameters (10Dq) in a high-spin and low-spin [Fe-II-N-6] complex

被引：159

作者：

Koenig, Edgar ^{[1
]}

Watson, K. J. ^{[2
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Phys Chem 2, D-8520 Erlangen, Germany

[2] Univ Copenhagen, HC Orsted Inst, Chem Lab 4, DK-2100 Copenhagen, Denmark

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 05期

关键词：

D O I：

10.1016/0009-2614(70)85191-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Preliminary but statistically significant results on the different Fe-N bond lengths R in a high-spin and low-spin form of Fe(bipy)(2)(NCS)(2) are reported (bipy = 2,2'-bipyridyl). The "ionic radius" of the low-spin Fe2+ ion is estimated. The relation between 10Dq and R-5 is satisfied within 2.6%.

引用

页码：457 / 459

页数：3

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