FORMAL 1,6-INSERTION OF AN ALKYLIDENECARBENE INTO A CARBON-HYDROGEN BOND - UNVEILING OF A STEPWISE REACTION-MECHANISM

被引:16
作者
GILBERT, JC
BLACKBURN, BK
机构
[1] Department of Chemistry, The University of Texas at Austin, Austin
关键词
D O I
10.1016/S0040-4039(00)97717-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The formation of 1,3-dimethylquinol-2-one (6a) by reaction of N-methyl-N-phenyl-2-oxopropanamide (1a) with diethyl (diazomethyl)phosphonate (2), an apparent CH insertion by an alkylidenecarbene, is shown to involve a stepwise rather than a concerted reaction pathway. © 1990.
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收藏
页码:4727 / 4730
页数:4
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