REDUCTION OF BENZYLIDENEANILINE OVER SUPPORTED PT CATALYSTS OBTAINED BY CHEMICAL-REDUCTION

被引:2
作者
ARAMENDIA, MA
BORAU, V
JIMENEZ, C
MARINAS, JM
RODERO, F
SEMPERE, ME
机构
[1] Department of Organic Chemistry, Faculty of Sciences, University of Córdoba, Córdoba
来源
REACTION KINETICS AND CATALYSIS LETTERS | 1990年 / 42卷 / 01期
关键词
D O I
10.1007/BF02137614
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reports a study on the reduction of benzyl-ideneaniline over novel supported Pt catalysts. The catalysts were reduced chemically and feature activities comparable to those of catalysts reduced under a hydrogen flow, but are much more resistant to deactivation processes. The reduction of benzylideneaniline was found to conform to a Langmuir-Hinshelwood kinetics of zero order in the substrate, namely ri=k0kPH2(1+kPH2)-1. © 1990 Akadémiai Kiadó.
引用
收藏
页码:33 / 38
页数:6
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