MELTING AND THE ELECTRONIC ABSORPTION OF BENZENE-ARGON CLUSTERS

被引：45

作者：

FRIED, LE

MUKAMEL, S

机构：

[1] Department of Chemistry, University of Rochester, Rochester

来源：

PHYSICAL REVIEW LETTERS | 1991年 / 66卷 / 18期

关键词：

D O I：

10.1103/PhysRevLett.66.2340

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The coexistence of sharp and broad features in the electronic spectrum of a chromophore embedded in a rare-gas cluster has been interpreted as a signature of solid-liquid phase coexistence in the melting transition. We perform molecular-dynamics simulations of benzene-Ar(N) clusters which show that the observed spectral features are instead dominated by inhomogeneous broadening due to various cluster configurations.

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页码：2340 / 2343

页数：4

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