SPIN-DENSITIES IN COPPER-NITRONYL NITROXIDE COMPLEXES

被引：3

作者：

BOUCHERLE, JX

RESSOUCHE, E

SCHWEIZER, J

GILLON, B

REY, P

机构：

[1] CENS,LAB LEON BRILLOUIN,F-91191 GIF SUR YVETTE,FRANCE

[2] CEN,DRFMC,SESAM,CC,F-38041 GRENOBLE,FRANCE

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 1993年 / 48卷 / 1-2期

关键词：

NITRONYL NITROXIDE FREE RADICALS; COPPER COMPLEXES; POLARIZED NEUTRON DIFFRACTION; SPIN DENSITY;

D O I：

10.1515/zna-1993-1-227

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The spin density in two copper-nitronyl nitroxide complexes, viz. bis (hexafluoroacetylacetonato)-(2,4,4,5,5-pentamethyl-1-oxy-imidazoline 3-oxide)-copper(II) and dichloro-bis(2-phenyl-4,4,5,5-tetra-methyl-1-oxy-imidazoline 3-oxide)-copper(II), has been determined by polarised-neutron diffraction. Spin populations and unpaired electron wave functions have been refined.

引用

页码：120 / 122

页数：3

共 7 条

[1] MODERATE FERROMAGNETIC EXCHANGE BETWEEN COPPER(II) AND A NITRONYL NITROXIDE IN A SQUARE-PYRAMIDAL ADDUCT - MO INTERPRETATION OF THE MECHANISM OF EXCHANGE IN COPPER(II) NITROXIDE COMPLEXES [J].