PALLADIUM(0)-CATALYZED CONVERSION OF VINYL TRIFLUOROMETHANESULFONATES INTO ALPHA,BETA-UNSATURATED NITRILES

被引：14

作者：

PIERS, E

FLEMING, FF

机构：

[1] Department of Chemistry, University of British Columbia, University Campus, Vancouver, BC V6T 1Z1

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1993年 / 71卷 / 11期

关键词：

D O I：

10.1139/v93-234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment (benzene, room temperature) of each of the vinyl trifluoromethanesulfonates 16-23 with dry lithium cyanide in the presence of catalytic amounts of tetrakis(triphenylphosphine)palladium(0) and the crown ether 12-crown-4 provides good to excellent yields of the corresponding (alpha,beta-unsaturated nitriles 24-31.

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页码：1867 / 1872

页数：6

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