THE SYNTHESIS OF RADERMACHOL

被引：28

作者：

JOSHI, BS ^{[1
]}

JIANG, QP ^{[1
]}

RHO, T ^{[1
]}

PELLETIER, SW ^{[1
]}

机构：

[1] UNIV GEORGIA,DEPT CHEM,ATHENS,GA 30602

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 26期

关键词：

D O I：

10.1021/jo00105a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Five different approaches to the preparation of 6,7-benzo-3,4-(1,4-dimethoxy-2,3-naphtho)-1,5-dioxosuberane (3), an intermediate needed for the synthesis of radermachol (1), the red pigment from the roots of Radermachera xylocarpa, are described. The synthesis of radermachol (1) has been accomplished from 1,4-nephthoquinone in 14 steps.

引用

页码：8220 / 8232

页数：13

共 36 条

[1]

BASHA A, 1977, TETRAHEDRON LETT, P4171

[2] STUDIES ON INTRA-MOLECULAR ALKYLATION .9. SYNTHESIS OF TRICYCLIC DIENONES SUITABLE FOR SYNTHESIS OF 13-HYDROXYGIBBERELLINS [J].