PREPARATION OF METHYL 1,3-DIEN-2-CARBOXYLATE BY THE PALLADIUM-CATALYZED CARBONYLATION OF 2,3-DIEN-1-OLS

被引:40
作者
NOKAMI, J
MAIHARA, A
TSUJI, J
机构
关键词
D O I
10.1016/S0040-4039(00)97917-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium-catalyzed carbonylation of methyl carbonates of 1,2-disubstituted 2,3-dien-1-ols (α-allenylic alcohols) proceeds at a room temperature under atmospheric pressure of carbon monoxide to afford 3,4-disubstituted 1,3-dien-2-carboxylates regioselectively in good yields. © 1990.
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页码:5629 / 5630
页数:2
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