PREPARATION OF METHYL 1,3-DIEN-2-CARBOXYLATE BY THE PALLADIUM-CATALYZED CARBONYLATION OF 2,3-DIEN-1-OLS

被引：40

作者：

NOKAMI, J

MAIHARA, A

TSUJI, J

机构：

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)97917-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed carbonylation of methyl carbonates of 1,2-disubstituted 2,3-dien-1-ols (α-allenylic alcohols) proceeds at a room temperature under atmospheric pressure of carbon monoxide to afford 3,4-disubstituted 1,3-dien-2-carboxylates regioselectively in good yields. © 1990.

引用

页码：5629 / 5630

页数：2

共 5 条

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[2] KLEIJN H, 1983, RECL TRAV CHIM PAY B, V102, P378
[3] ALLYLATION OF ALDEHYDES AND KETONES IN THE PRESENCE OF WATER BY ALLYLIC BROMIDES, METALLIC TIN, AND ALUMINUM
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[4] REACTION OF PROPARGYL BROMIDE AND TRIMETHYLSILYLPROPARGYL IODIDE WITH METALLIC TIN, ALUMINUM, AND ALDEHYDES OR KETONES - SELECTIVE SYNTHESIS OF BETA-ACETYLENE, BETA-TRIMETHYLSILYLACETYLENE, AND ALPHA-TRIMETHYLSILYLALLENE ALCOHOLS
NOKAMI, J
TAMAOKA, T
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[J]. CHEMISTRY LETTERS, 1984, (11) : 1939 - 1942
[5] PALLADIUM-CATALYZED DECARBOXYLATION-CARBONYLATION OF ALLYLIC CARBONATES TO FORM BETA,GAMMA-UNSATURATED ESTERS
TSUJI, J
SATO, K
OKUMOTO, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (08) : 1341 - 1344

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