CHEMICAL SYNTHESIS OF POLYMERS CONTAINING N-ETHYL-3.7-PHENOTHIAZINEDIYL GROUPS

被引：2

作者：

GRIGORAS, M ^{[1
]}

FARCAS, A ^{[1
]}

CIANGA, I ^{[1
]}

SIMIONESCU, CI ^{[1
]}

机构：

[1] PETRU PONI INST MACROMOLEC CHEM, ALLEY GR GHICA VODA 41A, R-6600 IASI, ROMANIA

来源：

POLYMER BULLETIN | 1991年 / 26卷 / 02期

关键词：

D O I：

10.1007/BF00297517

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(N-ethyl 3.7-phenothiazinediyl) (1) and poly(N-ethyl 3.7-phenothiazinediyl-co-acetylene) (2) were synthesized by homo- and copolycondensation of 3.7-dibromo N-ethylphenothiazine and 1.2-dibromoethene using a Grignard reaction and NiCl2 or NiCl2.2PPh3 as catalyst. Polymers are soluble in common organic solvents and after doping with iodine have an electrical conductivity of 10(-7) -10(-6) ohm -1.cm-1.

引用

页码：139 / 143

页数：5

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