THE RELATIVE AND ABSOLUTE-CONFIGURATIONS OF STEREOCENTERS IN CARYOPHYLLOSE

被引：22

作者：

ADINOLFI, M

CORSARO, MM

DECASTRO, C

EVIDENTE, A

LANZETTA, R

MANGONI, L

PARRILLI, M

机构：

[1] UNIV NAPLES FEDERICO II,DIPARTIMENTO CHIM ORGAN & BIOL,I-80134 NAPLES,ITALY

[2] UNIV NAPLES FEDERICO II,DIPARTIMENTO SCI CHIMICOAGR,I-80055 PORTICI,ITALY

来源：

CARBOHYDRATE RESEARCH | 1995年 / 274卷

关键词：

CARYOPHYLLOSE; LIPOPOLYSACCHARIDE; CARYOPHYLLI; CONFIGURATION; DEOXY SUGAR;

D O I：

10.1016/0008-6215(95)00127-F

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The complete stereochemistry of the monosacccharide 3,6,10-trideoxy-4-C-[(R)-1-hydroxyethyl]-D-erythro-D-gulo-decose, named caryophyllose, obtained from the lipopolysaccharide fraction of Pseudomonas caryophylli is reported. The relative stereochemistry was inferred by H-1 NMR analysis and the absolute configuration was independently elucidated by Mosher's and Exciton Chiral Coupling methods.

引用

页码：223 / 232

页数：10

共 8 条

[1] A NOVEL 4-C-BRANCHED SUGAR FROM THE LIPOPOLYSACCHARIDE OF THE BACTERIUM PSEUDOMONAS-CARYOPHYLLI [J].