TUNNELING SPECTROSCOPY STUDY OF THE ADSORPTION OF FERROCYANIDE FROM WATER SOLUTION BY AL2O3

被引：18

作者：

HIPPS, KW ^{[1
]}

MAZUR, U ^{[1
]}

PEARCE, MS ^{[1
]}

机构：

[1] WASHINGTON STATE UNIV, CHEM PHYS RECH INST, PULLMAN, WA 99163 USA

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 2-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)87232-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tunneling spectra of Fe(12C15N)4-6 and Fe(12C14N)4-6 adsorbed on Al2O3 from dilute H2 16O and 50% H2 18O solutions are compared to infrared and Raman spectra of the K4Fe(CN)6 salt. CN stretching frequencies and isotopic shifts indicate that the iron remains in the divalent state after adsorption. IETS provides more information than IR, and somewhat different information than Raman spectroscopy. © 1979.

引用

页码：433 / 437

页数：5

共 20 条

[1] SURVEY STUDY OF VIBRATIONAL SPECTRA OF SOME AQUO-HALOGENO-COMPLEXES
ADAMS, DM
LOCK, PJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (17): : 2801 - &
[2] ADANE A, 1975, SOLID STATE COMMUN, V16, P1071, DOI 10.1016/0038-1098(75)90006-X
[3] [Anonymous], 1978, INFRARED RAMAN SPECT
[4] NATURE OF OXIDE BARRIER IN INELASTIC ELECTRON-TUNNELING SPECTROSCOPY
BOWSER, WM
WEINBERG, WH
[J]. SURFACE SCIENCE, 1977, 64 (02) : 377 - 392
[5] DUBIN AJ, 1978, CHEM WASTE WATER TEC, pCH20
[6] RAMAN SPECTRA AND VIBRATIONAL ASSIGNMENTS OF HEXACYANO-COMPLEXES
GRIFFITH, WP
TURNER, GT
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (06): : 858 - &
[7] INELASTIC ELECTRON-TUNNELING
HANSMA, PK
[J]. PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1977, 30 (02): : 145 - 206
[8] INELASTIC ELECTRON-TUNNELING SPECTROSCOPY OF CARBON-MONOXIDE CHEMISORBED ON ALUMINA-SUPPORTED TRANSITION-METALS
HANSMA, PK
KASKA, WC
LAINE, RM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (19) : 6064 - 6065
[9] MOLECULAR VIBRATION SPECTRA BY ELECTRON TUNNELING
JAKLEVIC, RC
LAMBE, J
[J]. PHYSICAL REVIEW LETTERS, 1966, 17 (22) : 1139 - &
[10] JONES L, 1971, INORGANIC VIBRATIONA, V1

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