RELATIONS BETWEEN CURIE-TEMPERATURE AND CHEMICAL-BOND IN OCTAHEDRAL MONODIMENSIONAL FERROELECTRICS

被引:18
作者
RAVEZ, J
机构
[1] Université Bordeaux I, cours de la Libération, 33405, Talence Cedex
关键词
D O I
10.1080/01411599108207711
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Octahedral monodimensional ferroelectrics are an important group of compounds due to their great number, the theoretical studies made on them, their property modulation by various ionic substitutions and their applications. They belong to different structural families: perovskites, tetragonal tungsten bronzes, LiNbO3… The Curie temperature is related to the chemical bond of these materials. Various aspects are described. They concern the influence of the size, the charge, the coordination, the electronic configuration of the cations, either in or out of the octahedron, the bond covalency and the degree of cationic order. © 1991, Taylor & Francis Group, LLC. All rights reserved.
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页码:53 / 64
页数:12
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