DENSITIES AND EXCESS MOLAR VOLUMES OF 2-METHOXYETHANOL WATER BINARY-MIXTURES

被引：19

作者：

CORRADINI, F ^{[1
]}

FRANCHINI, G ^{[1
]}

MARCHESELLI, L ^{[1
]}

TASSI, L ^{[1
]}

TOSI, G ^{[1
]}

机构：

[1] UNIV MODENA,DEPT CHEM,I-41100 MODENA,ITALY

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1992年 / 45卷 / 07期

关键词：

D O I：

10.1071/CH9921109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Densities (rho) are reported for the 2-methoxyethanol (component 1)/water (component 2) solvent system, over the full composition range (0 less-than-or-equal-to X1 less-than-or-equal-to 1) at temperatures (t) from -10 to +80-degrees-C. The experimental data have been fitted by three empirical relations that represent the functions rho = rho(t), rho = rho(X1), rho = rho(t, Xi), and the excess volume values by a Redlich-Kister equation. The 1:2 2-methoxyethanol/water adduct appears to be stable throughout the temperature range.

引用

页码：1109 / 1117

页数：9

共 15 条

[1] Byers W. H., 1939, J CHEM PHYS, V7, P175
[2] DIELECTRIC-CONSTANTS AND DENSITIES OF AQUEOUS MIXTURES OF 2-ALKOXYETHANOLS AT 25-DEGREES-C
DOUHERET, G
PAL, A
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (01) : 40 - 43
[3] FRANKS F, 1967, PHYSICO CHEM PROCESS
[4] GROLLIER JPE, 1977, INT DATA B
[5] FREE-ENERGIES AND ENTROPIES OF TRANSFER OF HYDROGEN HALIDES FROM WATER TO AQUEOUS 2-METHOXY ETHANOL AND STRUCTUREDNESS OF THE SOLVENTS
GUHA, PK
KUNDU, KK
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (04): : 798 - 803
[6] GUPTA DD, 1988, J CHEM SOC F1, V84, P1057
[7] HALL B, 1987, TSP TIMES SERIES PRO
[8] IONIC EQUILIBRIA OF PICRIC ACID IN MIXED AMPHIPROTIC SOLVENTS - THE 2-METHOXYETHANOL-WATER SOLVENT SYSTEM
MARCHETTI, A
PICCHIONI, E
TASSI, L
TOSI, G
[J]. ANALYTICAL CHEMISTRY, 1989, 61 (17) : 1971 - 1977
[9] REFRACTIVE-INDEX AND EXCESS VOLUME FOR BINARY-LIQUID MIXTURES .1. ANALYSES OF NEW AND OLD DATA FOR BINARY-MIXTURES
NAKATA, M
SAKURAI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 : 2449 - 2457
[10] MICROHETEROGENIETY IN AQUEOUS MIXTURES OF HYDROPHOBIC SOLUTES THROUGH VISCOSITY STUDIES
RAMANAMURTI, MV
PRABHU, PVSS
BAHADUR, SL
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (07) : 2341 - 2345

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