6-DIMETHYLAMINO-6-LITHIOFULVENE, A NOVEL 6-FULVENYL ANION OF POTENTIAL SYNTHETIC UTILITY

被引：8

作者：

KAWASE, T ^{[1
]}

FUJINO, S ^{[1
]}

ODA, M ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期

关键词：

D O I：

10.1016/0040-4039(90)87030-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 6.6-bis(dimethylamino)fulvene with 2.2 equiv. of lithium napthalenide in THF generates, via two-electron reduction and deamination, 6-dimethylamino-6 lithiofulvene which is a new 6-fulvenyl anion of potential utility for the synthesis of a variety of 6-aminofulvenes and related compounds. © 1990.

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页码：545 / 548

页数：4

相关论文

共 7 条

[1] 1,2-BENZYNES FROM 6-HALOPENTAFULVENES [J].

HAFNER, K ;

KRIMMER, HP ;

STOWASSER, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (06) :490-491

[2]

HAFNER K, 1973, ORG SYNTH, V5, P431

[3] REDUCTIVE COUPLING OF 6-DIMETHYLAMINOFULVENES FURNISHING 6,6'-BIFULVENYLS [J].

KAWASE, T ;

NISATO, N ;

ODA, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (16) :1145-1146

[4] REDUCTION OF 6,6-DISUBSTITUTED FULVENES AND 1,2-BENZOHEPTAFULVENE BY NAPHTHALENE RADICAL-ANION [J].

OKU, A ;

YOSHIDA, M ;

MATSUMOTO, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1979, 52 (02) :524-528

[5] NEW SYNTHETIC REACTIONS - CHEMOSELECTIVE APPROACH TO CLEAVAGE ALPHA TO A CARBONYL GROUP VIA BETA-KETO SULFIDES - PREPARATION OF 1,2-DIKETONES [J].

TROST, BM ;

MASSIOT, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (13) :4405-4412

[6] THE CAPTODATIVE EFFECT [J].

VIEHE, HG ;

JANOUSEK, Z ;

MERENYI, R ;

STELLA, L .

ACCOUNTS OF CHEMICAL RESEARCH, 1985, 18 (05) :148-154

[7]

Zeller K. P., 1985, METHOD ORGAN CHEM, V5/2C, P504