STEREOSPECIFIC SYNTHESIS OF ARYLIDENE AND ALLYLIDENE CYCLOPENTANES BY A PALLADIUM-CATALYZED CYCLIZATION

被引：52

作者：

FOURNET, G

BALME, G

VANHEMELRYCK, B

GORE, J

机构：

[1] UNIV LYON 1,ECOLE SUPER CHIM IND LYON,CNRS,CHIM ORGAN LAB 1,F-69622 VILLEURBANNE,FRANCE

[2] ATOCHEM,CTR RECH RHONE ALPES,F-69310 PIERRE BENITE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)97827-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinyl and aryl halides react with ε-acetylenic β-diesters, β-keto esters and βsulfonylesters in the presence of a Pd(o) catalyst leading in good yields to the title compounds. The acetylenic homolog containing an additional carbon leads in the same conditions to a cyclohexane, but this process then competes with the arylation of the terminal acetylenic carbon. © 1990.

引用

页码：5147 / 5150

页数：4

共 9 条

[1]

BALME G, IN PRESS

[2] INTRAMOLECULAR ARYLATIONS OF SOFT ENOLATES CATALYZED BY ZEROVALENT PALLADIUM [J].