DEHALOSILYLATION REACTIONS INVOLVING E(SIME3)3 AND PH2INCL - SYNTHESIS AND X-RAY STRUCTURES OF [PH2INE(SIME3)2]2 (E = P OR AS)

被引：27

作者：

WELLS, RL

MCPHAIL, AT

JONES, LJ

SELF, MF

机构：

[1] Department of Chemistry, Paul M. Gross Chemical Laboratory, Duke University, Durham

来源：

POLYHEDRON | 1993年 / 12卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)81620-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Combining P(SiMe3)3 or As(SiMe3)3 With Ph2InC] in a 1 : 1 mole ratio results in the elimination of Me3SiCl via a dehalosilylation reaction to yield [Ph2InP(SiMe3)2]2 (I) and [Ph2InAs(SiMe3)2]2 (II), respectively. X-ray structures were determined for I and II. The (InP)2 core of dimer I is planar, whereas in dimer II the (InAs)2 ring is slightly puckered.

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页码：141 / 147

页数：7

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