THE PI AND SIGMA BONDING MODES OF MESO-OCTAETHYLPORPHYRINOGEN TO TRANSITION-METALS - THE X-RAY STRUCTURE OF A MESO-OCTAETHYLPORPHYRINOGEN ZIRCONIUM(IV) COMPLEX AND OF THE PARENT MESO-OCTAETHYLPORPHYRINOGEN LIGAND

被引：61

作者：

JACOBY, D

FLORIANI, C

CHIESIVILLA, A

RIZZOLI, C

机构：

[1] UNIV LAUSANNE,CHIM SECT,PL CHATEAU 3,CH-1005 LAUSANNE,SWITZERLAND

[2] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFRATTOMETRI,IST STRUTTURIST CHIM,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 11期

关键词：

D O I：

10.1039/c39910000790

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The meso-octaethylporphyrinogen tetraanion provides sigma and pi binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen-zirconium(IV) complex containing two eta-5 and two sigma metal-bonded pyrrolyl anions.

引用

页码：790 / 792

页数：3

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