SYNTHESIS OF BLOCK COPOLYMERS BY COMBINATION OF AN ACTIVATED MONOMER AND FREE-RADICAL POLYMERIZATION MECHANISM

被引：51

作者：

YAGCI, Y ^{[1
]}

SERHATLI, IE ^{[1
]}

KUBISA, P ^{[1
]}

BIEDRON, T ^{[1
]}

机构：

[1] POLISH ACAD SCI, CTR MOLEC & MACROMOLEC STUDIES, PL-90362 BOCZNA 5, POLAND

来源：

MACROMOLECULES | 1993年 / 26卷 / 10期

关键词：

D O I：

10.1021/ma00062a001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Epichlorohydrin (ECH) was polymerized by an activated monomer mechanism (AM) in the presence of 4,4'-azobis(4-cyanopentanol). Spectroscopic and degradation studies showed that polymers obtained via this initiation method contained an azo linkage in the main chain. These prepolymers were employed in the polymerization of styrene (St) to yield block copolymers.

引用

页码：2397 / 2399

页数：3

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